حذف یون کادمیم از محلول آبی با استفاده از نانوذرات مغناطیسی نیکل فریت دارای اتصال عرضی با کیتوزان

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانش‌آموخته کارشناسی ارشد مهندسی محیط زیست، دانشکده محیط زیست، واحد علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران

2 استادیار، گروه شیمی، دانشکده علوم پایه، واحد ورامین- پیشوا، دانشگاه آزاد اسلامی، ورامین، ایران

3 استادیار، گروه منابع آب، دانشکده محیط زیست، دانشگاه آزاد اسلامی، واحد علوم و تحقیقات، تهران، ایران

4 دانشیار، گروه شیمی، دانشکده علوم پایه، دانشگاه آزاد اسلامی، واحد ورامین- پیشوا، ورامین، ایران

چکیده

کادمیم یکی از فلزات سنگین تجزیه‌ناپذیر و بسیار سمّی است که از منابع مختلف وارد محیط‌های آبی می‌شود. دستیابی به ذخایر آب پاک و سالم مستلزم در نظر گرفتن تمهیداتی برای حذف کادمیم از پساب‌ها، پیش از تخلیه در محیط زیست است. در این پژوهش، نانوکامپوزیت مغناطیسی NiFe2O4-CS با واکنش ایجاد اتصال عرضی میان کیتوزان و نانوذرات نیکل فریت (NiFe2O4) با استفاده از گلوتارآلدئید به‌عنوان عامل ایجادکننده اتصال عرضی تهیه شد. ساختار، مورفولوژی، و رفتار مغناطیسی NiFe2O4-CS  با آنالیزهای FTIR، XRD، FE-SEM، EDX، و VSM مشخص شد. ویژگی جذب سطحی یون‌های کادمیم روی کامپوزیت
CS–NiFe2O4 و عوامل مؤثر بر آن نظیر pH، زمان تماس، غلظت اولیه کادمیم، و حضور یون‌های فلزی خارجی به طور کامل بررسی شد. بازده حذف کادمیم با غلظت اولیه 10 میلی‌گرم در لیتر درpH  برابر 7 و زمان 60 دقیقه با NiFe2O4-CS به 95 درصد رسید. چگالی بالای آمین و هیدروکسیل در کیتوزان، تشکیل کی‌لیت با یون‌های کادمیم را تسهیل می‌سازد و بازده فرایند جذب سطحی را افزایش می‌دهد. مدل سینتیکی شبه مرتبه اول، برازش بهتری با داده‌های تجربی جذب داشت و داده‌های تعادلی با همدمای جذبی لانگمیر به خوبی توصیف شدند. نتایج جذب/واجذب نشان داد که NiFe2O4-CS تهیه شده قابلیت استفاده مجدد در فرایند جذب سطحی را دارا است. مطابق نتایج این پژوهش، NiFe2O4-CS  می‌تواند به‌عنوان یک جاذب بالقوه مؤثر در حذف کادمیم از پساب مورد استفاده قرار گیرد.

کلیدواژه‌ها

عنوان مقاله [English]

Removal of Cd (II) Ion from Aqueous Solution Using Nickel Ferrite Magnetic Nanoparticles Cross–Linked Chitosan

نویسندگان [English]

  • Ashraf Homayonfard 1
  • Mahsasadat Miralinaghi 2
  • Reza Haji Seyed Mohammad Shirazi 3
  • Elham Moniri 4
1 Former Graduate Student of Environmental Engineering, Dept. of Environmental Engineering, Tehran Science and Research Branch, Islamic Azad University, Tehran, Iran
2 Assist. Prof., Dept. of Chemistry, Varamin-Pishva Branch, Islamic Azad University, Varamin, Iran
3 Assist. Prof., Dept. of Environmental Engineering, Tehran Science and Research Branch, Islamic Azad University, Tehran, Iran
4 Assoc. Prof., Dept. of Chemistry, Varamin-Pishva Branch, Islamic Azad University, Varamin, Iran
چکیده [English]

Cadmium is one of the non-biodegradable and extremely toxic heavy metals that enter into the aquatic environment by various sources. In order to provide a safe and clean water supply to the public, there is a crucial need to take some measures for removal of cadmium from wastewaters prior to their disposal in the environment. In the present study, a NiFe2O4-CS magnetic nanocomposite was prepared by a cross–linking reaction of chitosan with nickel ferrite (NiFe2O4) nanoparticles using glutaraldehyde as the cross–linking agent. The structure, morphology, and magnetic behavior of the NiFe2O4-CS were characterized by FTIR, XRD, FE-SEM, EDX, VSM analysis. The adsorption property of Cd (II) onto NiFe2O4-CS composite and the different factors that affect the adsorption, such as pH value, contact time, initial Cd (II) concentration, and the presence of foreign metal ions were extensively investigated. The Cd (II) removal efficiency of 95% was obtained within 60 min at pH 7.0 with initial Cd (II) concentration of 10 mg/L using CS/NiFe2O4. High amine and hydroxyl density of chitosan facilitated the chelation with Cd (II) ions, resulting in efficient adsorption. The pseudo-second-order kinetic model provided the best fit to experimental adsorption data and the equilibrium data could be well described by Langmuir adsorption isotherm. Adsorption/desorption results demonstrated that reusability of prepared NiFe2O4-CS was considerable. The results showed that NiFe2O4-CS could be employed as an effective and potential adsorbent for application in the removal of Cd (II) from wastewater.

کلیدواژه‌ها [English]

  • Wastewater Treatment
  • Adsorption
  • Magnetic Nanocomposite
  • Heavy Metals

مراجع

Ahmed, M. J. K. & Ahmaruzzaman, M. 2016. A review on potential usage of industrial waste materials for binding heavy metal ions from aqueous solutions. Journal of Water Process Engineering, 10, 39-47.
Carolin, C. F., Kumar, P. S., Saravanan, A., Joshiba, G. J. & Naushad, M. 2017. Efficient techniques for the removal of toxic heavy metals from aquatic environment: a review. Journal of Environmental Chemical Engineering, 5, 2782-2799.
Changmai, M. & Purkait, M. K. 2017. Kinetics, equilibrium and thermodynamic study of phenol adsorption using NiFe 2O4 nanoparticles aggregated on PAC. Journal of Water Process Engineering, 16, 90-97.
Crini, G. & Badot, P.-M. 2008. Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: a review of recent literature. Progress in Polymer Science, 33, 399-447.
Dananjaya, S. H. S., Kumar, R. S., Yang, M., Nikapitiya, C., Lee, J. & De Zoysa, M. 2018. Synthesis, characterization of ZnO-chitosan nanocomposites and evaluation of its antifungal activity against pathogenic Candida albicans. International Journal of Biological Macromolecules, 108, 1281-1288.
Fan, C., Li, K., Li, J., Ying, D., Wang, Y. & Jia, J. 2017. Comparative and competitive adsorption of Pb (II) and Cu(II) using tetraethylenepentamine modified chitosan/CoFe2O4 particles. Journal of Hazardous Materials, 326, 211-220.
Gupta, V. K. & Suhas 2009. Application of low-cost adsorbents for dye removal--a review. Journal of Environmental Managment, 90, 2313-2342.
He, J., Li, Y., Wang, C., Zhang, K., Lin, D., Kong, L., et al. 2017. Rapid adsorption of Pb, Cu and Cd from aqueous solutions by β-cyclodextrin polymers. Applied Surface Science, 426, 29-39.
Homayonfard, A., Miralinaghi, M., Shirazi, R. H. S. M. & Moniri, E. 2018. Efficient removal of cadmium (II) ions from aqueous solution by CoFe2O4/chitosan and NiFe2O4/chitosan composites as adsorbents. Water Science and Technology, 78, 2297-2307.
Hu, J., Chen, C., Zhu, X. & Wang, X. 2009. Removal of chromium from aqueous solution by using oxidized multiwalled carbon nanotubes. Journal of Hazardous Materials, 162, 1542-1550.
Ihsanullah, Abbas, A., Al-Amer, A. M., Laoui, T., Al-Marri, M. J., Nasser, M. S., et al. 2016. Heavy metal removal from aqueous solution by advanced carbon nanotubes: critical review of adsorption applications. Separation and Purification Technology, 157, 141-161.
Inyang, M. I., Gao, B., Yao, Y., Xue, Y., Zimmerman, A., Mosa, A., et al. 2015. A review of biochar as a low-cost adsorbent for aqueous heavy metal removal. Critical Reviews in Environmental Science and Technology, 46, 406-433.
Jafari, A. J., Kakavandi, B., Kalantary, R. R., Gharibi, H., Asadi, A., Azari, A., et al. 2016. Application of mesoporous magnetic carbon composite for reactive dyes removal: process optimization using response surface methodology. Korean Journal of Chemical Engineering, 33, 2878-2890.
Kahrizi, P., Mohseni-Shahri, F. S. & Moeinpour, F. 2018. Adsorptive removal of cadmium from aqueous solutions using NiFe2O4/hydroxyapatite/graphene quantum dots as a novel nano-adsorbent. Journal of Nanostructure in Chemistry, 8, 441-452.
Kazeminezhad, I., Ahmadizadeh, S. & Babaie, A. A. 2014. Application of magnetic hydroxyapatite nanoparticles for removal of Cd2+from aqueous solutions. Journal of Environmental Studies, 40, 739-750.
Kefeni, K. K., Mamba, B. B. & Msagati, T. A. M. 2017. Application of spinel ferrite nanoparticles in water and wastewater treatment: a review. Separation and Purification Technology, 188, 399-422.
Li, H., Zhang, L., Sun, Z., Liu, Y., Yang, B. & Yan, S. 2015a. One-step synthesis of magnetic 1,6-hexanediamine-functionalized reduced graphene oxide–zinc ferrite for fast adsorption of Cr (vi). RSC Advances, 5, 31787-31797.
Li, L., Wang, Z., Ma, P., Bai, H., Dong, W. & Chen, M. 2015b. Preparation of polyvinyl alcohol/chitosan hydrogel compounded with graphene oxide to enhance the adsorption properties for Cu (II) in aqueous solution. Journal of Polymer Research, 22, 150.
Li, L. H., Deng, J. C., Deng, H. R., Liu, Z. L. & Xin, L. 2010. Synthesis and characterization of chitosan/ZnO nanoparticle composite membranes. Carbohydract Research, 345 (8), 994-998.
Lim, A. P. & Aris, A. Z. 2013. A review on economically adsorbents on heavy metals removal in water and wastewater. Reviews in Environmental Science and Bio/Technology, 13, 163-181.
Lingamdinne, L. P., Koduru, J. R., Choi, Y.-L., Chang, Y.-Y. & Yang, J.-K. 2016. Studies on removal of Pb (II) and Cr (III) using graphene oxide based inverse spinel nickel ferrite nano-composite as sorbent. Hydrometallurgy, 165, 64-72.
Liu, F., Zhou, K., Chen, Q., Wang, A. & Chen, W. 2018. Comparative study on the synthesis of magnetic ferrite adsorbent for the removal of Cd(II) from wastewater. Adsorption Science and Technology, 36, 1456-1469.
Liu, Y., Xu, L., Liu, J., Liu, X., Chen, C., Li, G., et al. 2016. Graphene oxides cross-linked with hyperbranched polyethylenimines: preparation, characterization and their potential as recyclable and highly efficient adsorption materials for lead(II) ions. Chemical Engineering Journal, 285, 698-708.
Mehta, D., Mazumdar, S. & Singh, S. K. 2015. Magnetic adsorbents for the treatment of water/wastewater-a review. Journal of Water Process Engineering, 7, 244-265.
Miretzky, P. & Cirelli, A. F. 2009. Hg (II) removal from water by chitosan and chitosan derivatives: a review. Journal of Hazardous Materials, 167, 10-23.
Mohan, D & Pittman, C. U. J. 2007. Arsenic removal from water/wastewater using adsorbents-a critical review. Journal of Hazardous Materials, 142, 1-53.
Mohan, D., Sarswat, A., Ok, Y. S. & Pittman, C. U. J. 2014. Organic and inorganic contaminants removal from water with biochar, a renewable, low cost and sustainable adsorbent-a critical review. Bioresource Technology, 160, 191-202.
Niu, C., Wu, W., Wang, Z., Li, S. & Wang, J. 2007. Adsorption of heavy metal ions from aqueous solution by crosslinked carboxymethyl konjac glucomannan. Journal of Hazardous Materials, 141, 209-214.
Reddy, D. H. & Lee, S. M. 2013. Application of magnetic chitosan composites for the removal of toxic metal and dyes from aqueous solutions. Advanced Colloid Interface Science, 201-202, 68-93.
Santhana K. Kumar, A. & Jiang, S.-J. 2015. Preparation and characterization of exfoliated graphene oxide–l-cystine as an effective adsorbent of Hg (II) adsorption. RSC Advances, 5, 6294-6304.
Santhosh, C., Kollu, P., Felix, S., Velmurugan, V., Jeong, S. K. & Grace, A. N. 2015. CoFe2O4 and NiFe2O4@graphene adsorbents for heavy metal ions – kinetic and thermodynamic analysis. RSC Advances, 5 (28), 28972-965.
Siddiqui, S. I. & Chaudhry, S. A. 2017. Iron oxide and its modified forms as an adsorbent for arsenic removal: a comprehensive recent advancement. Process Safety and Environmental Protection, 111, 592-626.
Sivashankar, R., Sathya, A. B., Vasantharaj, K. & Sivasubramanian, V. 2014. Magnetic composite an environmental super adsorbent for dye sequestration – a review. Environmental Nanotechnology, Monitoring & Management, 1-2, 36-49.
Springer, V., Pecini, E. & Avena, M. 2016. Magnetic nickel ferrite nanoparticles for removal of dipyrone from aqueous solutions. Journal of Environmental Chemical Engineering, 4, 3882-3890.
Towler, P. H., Smith, J. D. & Dixon, D. R. 1996. Magnetic recovery of radium, lead and polonium from seawater samples after preconcentration on a magnetic adsorbent of manganese dioxide coated magnetite. Analytica Chimica Acta, 328, 53-59.
Vilela, D., Parmar, J., Zeng, Y., Zhao, Y. & Sanchez, S. 2016. Graphene-based microbots for toxic heavy metal removal and recovery from water. Nano Letters, 16, 2860-2866.
Wang, L., Li, J., Wang, Y., Zhao, L. & Jiang, Q. 2012. Adsorption capability for Congo red on nanocrystalline MFe2O4 (M=Mn, Fe, Co, Ni) spinel ferrites. Chemical Engineering Journal, 181-182, 72-79.
Zavar Mousavi, S. H. & Lotfi, Z. 2015. Removal of nickel and cadmium from aqueous solution by modified magnetic nanoparticles. Journal of Water and Wastewater, 26 (1), 11-20. (In Persian)
مجله آب و فاضلاب
دوره 31، شماره 3 - شماره پیاپی 127
مرداد و شهریور 1399
صفحه 112-127

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