مجله آب و فاضلاب

مجله آب و فاضلاب

بررسی تجربی جداسازی فلزات سنگین از پساب‌ نفتی با کمک غشاهای کامپوزیت پلی‌سولفون اصلاح شده

مقالات آماده انتشار

نوع مقاله : مقاله پژوهشی

نویسندگان
مریم بیت سعدی 1
فریال نصرتی نیا 2
احمد خوشگرد 2
مهدی ارجمند 3
1 دانشجوی دکترا، گروه مهندسی شیمی، واحد تهران جنوب، دانشگاه آزاد اسلامی، تهران، ایران
2 استادیار، گروه مهندسی شیمی، واحد تهران جنوب، دانشگاه آزاد اسلامی، تهران، ایران
3 استاد، گروه مهندسی شیمی، واحد تهران جنوب، دانشگاه آزاد اسلامی، تهران، ایران
10.22093/wwj.2026.580397.3549
چکیده
پساب‌های نفتی شامل ترکیبات آلی فرار دیر تجزیه‌پذیر، هیدروکربن‌ها، مواد کلردار و ‌فلزات سنگین هستند. انتشار ترکیبات آلی به دلیل آثار مخرب زیست‌محیطی که دارند و خطراتی که برای کارکنان این مجتمع‌ها ایجاد می‌کنند، موردتوجه بسیاری از سازمان‌های پژوهشی و محیط‌زیست است. در این پژوهش ساخت غشاهای کامپوزیتی اصلاح شده برای حذف فلزات سنگین از پساب‌ صنعتی به‌طور آزمایشگاهی بررسی شد. غشاهای با روش پلیمریزاسیون بین سطحی ساخته شد و آنالیزهای FTIR، XRD، EDX، SEM و زاویه تماس انجام شد. با افزایش غلظت نانوذرات Fe3O4/APTES از صفر بهwt %3/0 زاویه تماس غشاهای نانوکامپوزیت از ◦74/3 به ◦54/4 کاهش یافت. بعد از گذشت زمان 60 دقیقه شار عبور آب از غشای M0 تقریباً L/m2.hr 91/25 و شار عبور آب از غشاهای M1، M2 و M3 به ترتیب 91/36، 103/98 وL/m2.hr 125/36 بود. عملکرد غشاهای متفاوت برای حذف فلزات سنگین استرانسیم (Sr)، مس (Cu)، سرب (Pb) و کبالت (Co) موجود در آب در شرایط عملیاتی فشار bar 10، دبی L/min 2، زمان 60 دقیقه و دمای محیط نشان داد، غشای اصلاح شده با غلظت wt%1/0 Fe3O4/APTES (M2) بهترین عملکرد را نسبت به سایر غشاها دارد. بیشترین درصد حذف فلزات سنگین با غشای M2 به دست آمد که برای حذف فلزات سنگینSr 57/36 درصد، Cu 86/56 درصد،Pb 72/64 درصد و Co 65/89 درصد است. غشای M2 می‌تواند حدود 8/21 درصد مقدار شار آب را در مقایسه با 2/8 درصد غشاء M0 بازیابی کند و این نشانگر عملکرد بالاتر غشای M2 در بهبودی شار آب عبوری از غشاء است.
کلیدواژه‌ها
غشا
نانوکامپوزیت
فلزات سنگین
پساب‌ نفتی
پلیمریزاسیون

عنوان مقاله English

Experimental Investigation of Heavy Metal Separation from Petroleum Wastewater Using Modified Polysulfone Composite Membranes

نویسندگان English

Maryam Beit Sady 1
Ferial Nosratinia 2
Ahmad Khoshgard 2
Mehdi Ardjmand 3
1 PhD. Sftudent, Dept. of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
2 Assist. Prof., Dept. of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
3 Prof., Dept. of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
چکیده English

Oil effluents contain persistent volatile organic compounds, hydrocarbons, chlorinated substances, and heavy metals. The emission of organic compounds is of interest to many research and environmental organizations due to their destructive environmental effects and the risks they pose to the workers of these complexes. In this study, the fabrication of modified composite membranes for the removal of heavy metals from industrial effluents was studied experimentally. Membranes were fabricated by interfacial polymerization method and FTIR, XRD, EDX, SEM and contact angle analyses were performed. By increasing the concentration of Fe3O4/APTES nanoparticles from 0 to 0.3 wt%, the contact angle of the nanocomposite membranes decreased from 3.74° to 4.54°. After 60 minutes, the water flux through the M0 membrane is approximately 25.91 L/m2.hr and the water flux through the M1, M2 and M3 membranes is 36.91, 98.103 and 36.125 L/m2.hr, respectively. The performance of different membranes for the removal of heavy metals-strontium (Sr), copper (Cu), lead (Pb) and cobalt (Co)-present in water under operating conditions of 10 bar pressure, 2 L/min flow rate, 60 minutes time and ambient temperature showed that the modified membrane with 0.1 wt% Fe3O4/APTES concentration (M2) has the best performance compared to other membranes. The highest percentage of heavy metal removal was obtained with the M2 membrane, achieving 36.57% for Sr, 56.86% for Cu, 64.72% Pb and 65.89% for heavy metals. The M2 membrane can recover about 21.8% of the water flux compared to 8.2% of the M0 membrane, indicating the higher performance of the M2 membrane in improving the water flux through the membrane.

کلیدواژه‌ها English

Membrane
Nanocomposite
Heavy Metals
Oil Wastewater
Polymerization
Amini, M., Etemadi, H., Akbarzadeh, A. and Yegani, R., 2017. Preparation and performance evaluation of high-density polyethylene/silica nanocomposite membranes in membrane bioreactor system. Biochemical Engineering Journal, 127, 196-205. https://doi.org/10.1016/j.bej.2017.08.015.
Azimian Kivi, M., Alinia, H., Jafarzadeh, Y. and Yegani, R., 2019. High‐density polyethylene membranes embedded with carboxylated and polyethylene glycol‐grafted nanodiamond to be used in membrane bioreactors. Journal of Applied Polymer Science, 136(35), 47914. https://doi.org/10.1002/app.47914.
Cheng, X., Zhang, Y., Shao, S., Lai, C., Wu, D., Xu, J. et al., 2023. Highly permeable positively charged nanofiltration membranes with multilayer structures for multiple heavy metal removals. Desalination, 548, 116266. https://doi.org/10.1016/j.desal.2022.116266.
Eshaghi Malekshah, R., Fahimirad, B. and Khaleghian, A., 2020. Synthesis, characterization, biomedical application, molecular dynamic simulation and molecular docking of Schiff base complex of Cu (II) supported on Fe3O4/SiO2/APTS. International Journal of Nanomedicine, 15, 2583-2603. https://doi.org/10.2147/IJN.S231062.
Etemadi, H., Yegani, R. and Seyfollahi, M., 2017. The effect of amino functionalized and polyethylene glycol grafted nanodiamond on anti-biofouling properties of cellulose acetate membrane in membrane bioreactor systems. Separation and Purification Technology, 177, 350-362. https://doi.org/10.1016/j.seppur.2017.01.013.
Fadaei, Z, Darai, A. and Pakravan, P., 2024. Adsorption removal of heavy metals using activated carbon derived from natural bitumen. Journal of Water and Wastewater, 35(4), 1-22. (In Persian). https://doi.org/10.22093/wwj.2025.487432.3447.
Fonouni, M., Etemadi, H., Yegani, R. and Zarin, S., 2017. Fouling characterization of TiO2 nanoparticle embedded polypropylene membrane in oil refinery wastewater treatment using membrane bioreactor (MBR). Desalination and Water Treatment, 90, 99-109. https://doi.org/10.5004/dwt.2017.21360.
Ghaedi, A. M., Panahimehr, M., Rayegan Shirazi Nejad, A., Hosseini, S. J., Vafaei, A. and Baneshi, M. M., 2018. Factorial experimental design for the optimization of highly selective adsorption removal of lead and copper ions using metal organic framework MOF-2 (Cd). Journal of Molecular Liquids, 272, 15-26. https://doi.org/10.1016/j.molliq.2018.09.051.
Ghanbari, M., Emadzadeh, D., Lau, W. J., Lai, S. O., Matsuura, T. and Ismail, A. F., 2015. Synthesis and characterization of novel thin film nanocomposite (TFN) membranes embedded with halloysite nanotubes (HNTs) for water desalination. Desalination, 358, 33-41. https://doi.org/10.1016/j.desal.2014.11.035.
Hajrasouliha, A. and Hosseinzadeh, M., 2025. Application of membrane bioreactor method for removal of pollutants from industrial wastewater treatment plant effluent. Journal of Water and Wastewater, 36(4), 79-96. (In Persian). https://doi.org/10.22093/wwj.2026.566014.3535.
He, W., Zhang, M., Du, H., Amrane, A., Yu, H. and Liu, Y., 2023. Anchoring nano-zeolite NaX particles on polydopamine-modified PVDF/PAN electrospun membranes for enhancing interception, adsorption and antifouling performance. Colloids and Surfaces a: Physicochemical and Engineering Aspects, 670, 131587. https://doi.org/10.1016/j.colsurfa.2023.131587.
Jafarzadeh, M., Soleimani, E., Norouzi, P., Adnan, R. and Sepahvand, H., 2015. Preparation of trifluoroacetic acid-immobilized Fe3O4@ SiO2–APTES nanocatalyst for synthesis of quinolines. Journal of Fluorine Chemistry, 178, 219-224. https://doi.org/10.1016/j.jfluchem.2015.08.007.
Jiang, Y., Zeng, Q., Biswas, P. and Fortner, J. D., 2019. Graphene oxides as nanofillers in polysulfone ultrafiltration membranes: shape matters. Journal of Membrane Science, 581, 453-461. https://doi.org/10.1016/j.memsci.2019.03.056.
Kemikli, N., Kavas, H., Kazan, S., Baykal, A. and Ozturk, R., 2010. Synthesis of protoporphyrin coated superparamagnetic iron oxide nanoparticles via dopamine anchor. Journal of Alloys and Compounds, 502(2), 439-444. https://doi.org/10.1016/j.jallcom.2010.04.192.
Kurtan, U. and Baykal, A., 2014. Fabrication and characterization of Fe3O4@APTES@PAMAM-Ag highly active and recyclable magnetic nanocatalyst: catalytic reduction of 4-nitrophenol. Materials Research Bulletin, 60, 79-87. https://doi.org/10.1016/j.materresbull.2014.08.016.
Lei, Q., Li, F., Shen, L., Yang, L., Liao, B. Q. and Lin, H., 2016. Tuning anti-adhesion ability of membrane for a membrane bioreactor by thermodynamic analysis. Bioresource Technology, 216, 691-698. https://doi.org/10.1016/j.biortech.2016.06.008.
Li, J., Hu, M., Pei, H., Ma, X., Yan, F., Dlamini, D. S. et al., 2020. Improved water permeability and structural stability in a polysulfone-grafted graphene oxide composite membrane used for dye separation. Journal of Membrane Science, 595, 117547. https://doi.org/10.1016/j.memsci.2019.117547.
Lü, T., Qi, D., Zhang, D., Lü, Y. and Zhao, H., 2018. A facile method for emulsified oil-water separation by using polyethylenimine-coated magnetic nanoparticles. Journal of Nanoparticle Research, 20, 88. https://doi.org/10.1007/s11051-018-4193-7.
Malas, R., Ibrahim, Y., Alnashef, I., Banat, F. and Hasan, S. W., 2020. Impregnation of polyethylene membranes with 1-butyl-3-methylimidazolium dicyanamide ionic liquid for enhanced removal of Cd2+, Ni2+ and Zn2+ from aqueous solutions. Journal of Molecular Liquids, 318, 113981. https://doi.org/10.1016/j.molliq.2020.113981.
Nayak, M. C., Isloor, A. M., Lakshmi, B., Marwani, H. M. and Khan, I., 2020. Polyphenylsulfone/multiwalled carbon nanotubes mixed ultrafiltration membranes: fabrication, characterization and removal of heavy metals Pb2+, Hg2+ and Cd2+ from aqueous solutions. Arabian Journal of Chemistry, 13(3), 4661-4672. https://doi.org/10.1016/j.molliq.2020.114991.
Padervand, M., 2021. Reusable porous Na(Si2Al)O6.xH2O/NiFe2O4 structure for selective removal of heavy metals from waste waters. Google Patents, United States. https://doi.org/10.1021/j.biortech.2021.06.008.
Parham, N., Panahi, H. A., Feizbakhsh, A. and Moniri, E., 2018. Synthesis of high generation thermo-sensitive dendrimers for extraction of rivaroxaban from human fluid and pharmaceutic samples. Journal of Chromatography A, 1545, 12-21. https://doi.org/10.1016/j.chroma.2018.02.050.
Prakash Karki, H., Prashad Ojha, D., Kumar Joshi, M. and Joo Kim, H., 2018. Effective reduction of p-nitrophenol by silver nanoparticle loaded on magnetic Fe3O4/ATO nano-composite. Applied Surface Science, 435, 599-608. https://doi.org/10.1016/j.apsusc.2017.11.166.
Rahimi-Kashkouli, Y., Rahbari-Sisakht, M. and Ghadami Jadval Ghadam, A., 2020. Thin film nanocomposite nanofiltration membrane incorporated with cellulose nanocrystals with superior anti-organic fouling affinity. Environmental Science: Water Research and Technology, 6(3), 715-723. https://doi.org/10.1039/c9ew00963a.
Rahimpour, A., Jahanshahi, M., Mollahosseini, A. and Rajaeian, B., 2012. Structural and performance properties of UV-assisted TiO2 deposited nano-composite PVDF/SPES membranes. Desalination, 285, 31-38. https://doi.org/10.1016/j.desal.2011.09.026.
Vatanpour, V., Faghani, S., Keyikoglu, R. and Khataee, A., 2021. Enhancing the permeability and antifouling properties of cellulose acetate ultrafiltration membrane by incorporation of ZnO@ graphitic carbon nitride nanocomposite. Carbohydrate Polymers, 256, 117413. https://doi.org/10.1016/j.carbpol.2020.117413.
Wang, Y., Su, P., Wang, S., Wu, J., Huang, J. and Yang, Y., 2013. Dendrimer modified magnetic nanoparticles for immobilized BSA: a novel chiral magnetic nano-selector for direct separation of racemates. Journal of Materials Chemistry B, 1(38), 5028-5035. https://doi.org/10.1039/c3tb20889c.
Wu, S., Li, K., Shi, W. and Cai, J., 2022. Preparation and performance evaluation of chitosan/polyvinylpyrrolidone/polyvinyl alcohol electrospun nanofiber membrane for heavy metal ions and organic pollutants removal. International Journal of Biological Macromolecules, 210, 76-84. https://doi.org/10.1016/j.ijbiomac.2022.05.017.
Yan, F., Pei, H., Pei, Y., Li, T., Li, J., He, B. et al., 2015. Preparation and characterization of polysulfone-graft-4′-aminobenzo-15-crown-5-ether for lithium isotope separation. Industrial and Engineering Chemistry Research, 54(13), 3483-3489. https://doi.org/10.1021/acs.iecr.5b00314.
مجله آب و فاضلاب

مقالات آماده انتشار، پذیرفته شده
انتشار آنلاین از 23 دی 1404