مجله آب و فاضلاب

مجله آب و فاضلاب

ساخت غشای نانوکامپوزیت با افزودن نانوذرات اصلاح شده زئولیت به‌منظور تصفیه نفت از پساب‌های نفتی با استفاده از فرایند اولترافیلتراسیون

مقالات آماده انتشار

نوع مقاله : مقاله پژوهشی

نویسندگان
فاخر موسوی 1
مصطفی نریمانی 2
داریوش عمادزاده 3
1 دانشجوی دکترا، گروه مهندسی شیمی، واحد امیدیه، دانشگاه آزاد اسلامی، امیدیه، ایران
2 استادیار، گروه مهندسی شیمی، واحد امیدیه، دانشگاه آزاد اسلامی، امیدیه، ایران
3 استادیار، گروه مهندسی شیمی، واحد گچساران، دانشگاه آزاد اسلامی، گچساران، ایران
10.22093/wwj.2026.580483.3550
چکیده
نقش بسیار مؤثر جداسازی غشایی در تصفیه پساب‌های نفتی ثابت شده است، اگرچه رسوب‌گذاری همچنان یک چالش پایدار است. در این پژوهش اختلاط نانوذرات زئولیت S-β در یک غشای اولترافیلتراسیون، تشکیل یک نانوکامپوزیت برای مقابله با رسوب و افزایش بازیابی شار آب بررسی شد. نانوذرات متخلخل با استفاده از روش‌های سل- ژل هیدروترمال سنتز شدند که دارای سطح قابل‌توجه 450 مترمربع برگرم و اندازه‌های منافذی از 50 تا 175 نانومتر بر اساس نتایج BET بودند. این نانوذرات با استفاده از تکنیک وارونگی فاز در غشاها در غلظت‌های مختلف ادغام شدند. وجود S-زئولیت در غشاء از طریق آنالیزهای FITR، EDX وSEM تأیید شد. غشای نانوکامپوزیتی S-β1 خواص ضد رسوبی فوق‌العاده‌ای را به‌ویژه در غلظت‌های بیشتر پساب نفتی، از خود نشان داد که در مقایسه با سایر غشاها این غشاء، بازیابی شار آب 100 درصد در غلظت ppm50 و 72 درصد در غلظت ppm 1000 را ثبت کرد. این موفقیت را می‌توان به افزایش آب‌دوستی و اندازه منافذ بهینه غشاء (متوسط منافذ nm 3±13) نسبت داد که به‌طور مؤثر مانع تشکیل رسوب می‌شود. نتایج به‌دست‌ آمده مزایای قابل‌توجه نانوکامپوزیت را در کاهش رسوب‌گذاری و بهبود بازیابی شار در تصفیه پساب‌های نفتی نشان می‌دهد.
کلیدواژه‌ها
غشاء
نانوکامپوزیت
اولترافیلتراسیون
تصفیه پساب
S-β زئولیت
موضوعات

عنوان مقاله English

Synthesis and Characterization of Anti-Fouling Ultrafiltration Nanocomposite Membranes Integrated with S-β Zeolite Nanoparticles for Oily Wastewater Treatment

نویسندگان English

Fakher Mousavi 1
Mostafa Narimani 2
Daryoush Emadzadeh 3
1 PhD. Candidate, Dept. of Chemical Engineering, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran
2 Assist. Prof., Dept. of Chemical Engineering, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran
3 Assist. Prof., Dept. of Chemical Engineering, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran
چکیده English

Membrane separation has been proven to be highly effective in oily wastewater treatment, although fouling remains a persistent challenge. This study explored the incorporation of S-βzeolite nanoparticles into an ultrafiltration membrane, forming a nanocomposite to tackle fouling and enhance water flux recovery. Porous nanoparticles were synthesized using sol-gel and hydrothermal methods, featuring a remarkable surface area of 450 m2/g and pore sizes ranging from 50 to 175 nm according to BET results. These nanoparticles were integrated into the membranes at various concentrations using the phase inversion technique. The presence of S-zeolite in the membrane was confirmed through FTIR, EDX and SEM analyses. The S-β1 nanocomposite membrane demonstrated exceptional antifouling properties, particularly at higher concentrations of oily wastewater. Its outstanding performance is attributed to its enhanced hydrophilicity and average pore size of 13±3 nm, which prevents fouling formation. Compared to other membranes, S-β1 exhibited remarkable water flux recovery, reaching100% at an oil concentration of 50 ppm and 72% at 1000 ppm. These results highlight the significant advantages of this nanocomposite in reducing fouling and improving the water flux recovery in oily wastewater treatment.

کلیدواژه‌ها English

Membrane, Nanocomposite, Ultrafiltration, Wastewater Treatment, S-&beta
Zeolites
Ahmad, T., Guria, C. and Mandal, A., 2018. Optimal synthesis and operation of low-cost polyvinyl chloride/bentonite ultrafiltration membranes for the purification of oilfield produced water. Journal of Membrane Science, 564, 859–877. https://doi.org/10.1016/j.memsci.2018.07.093.
Bilstad, T. and Espedal, E., 1996. Membrane separation of produced water. Water Science and Technology, 34, 239-246. https://doi.org/10.1016/S0273-1223(96)00810-4.
Celik, E., Liu, L. and Choi, H., 2011. Protein fouling behavior of carbon nanotube/polyethersulfone composite membranes during water filtration. Water Research, 45(16), 5287-5294. https://doi.org/10.1016/j.watres.2011.07.036.
Chakrabarty, B., Ghoshal, A. K. and Purkait, M. K., 2008. Ultrafiltration of stable oil-in-water emulsion by polysulfone membrane. Journal of Membrane Science, 325(1), 427-437. https://doi.org/10.1016/j.memsci.2008.08.007.
Cornelissen, E. R., Harmsen, D., De Korte, K. F., Ruiken, C. J., Qin, J. J., Oo, H. et al., 2008. Membrane fouling and process performance of forward osmosis membranes on activated sludge. Journal of Membrane Science, 319, 158-168. https://doi.org/10.1016/j.memsci.2008.03.048.
Daraei, P. and Ghaemi, N., 2019. Synergistic effect of Cloisite 15A and 30B nanofillers on the characteristics of nanocomposite polyethersulfone membrane. Applied Clay Science, 172, 96–105. https://doi.org/10.1016/j.clay.2019.03.002.
Emadzadeh, D., Lau, W. J., Rahbari-Sisakht, M., Daneshfar, A., Ghanbari, M., Mayahi, A., et al. 2015. A novel thin film nanocomposite reverse osmosis membrane with superior anti-organic fouling affinity for water desalination. Desalination, 368, 106-113. https://doi.org/10.1016/j.desal.2014.11.019.
He, Y. and Jiang, Z. W., 2008. Technology review: treating oilfield wastewater. Filtration and Separation, 45(5), 14-16. https://doi.org/10.1016/S0015-1882(08)70174-5.
Holloway, R. W., Childress, A. E., Dennett, K. E. and Cath, T. Y., 2007. Forward osmosis for concentration of anaerobic digester centrate. Journal of Water Research, 41(17), 4005-4014. https://doi.org/10.1016/j.watres.2007.05.054.
Hou, D., Wang, Z., Wang, K., Wang, J. and Lin, S., 2018. Composite membrane with electrospun multiscale textured surface for robust oil-fouling resistance in membrane distillation. Journal of Membrane Science, 546, 179-187. https://doi.org/10.1016/j.memsci.2017.10.017.
Ikhsan, S. N. W., Yusof, N., Aziz, F., Misdan, N., Ismail, A. F., Lau, W. J. et al., 2018. Efficient separation of oily wastewater using polyethersulfone mixed matrix membrane incorporated with halloysite nanotube-hydrous ferric oxide nanoparticle. Separation and Purification Technology, 199, 161–169. https://doi.org/10.1016/j.seppur.2018.01.028.
Jamshidi Gohari, R., Halakoo, E., Lau, W. J., Kassim, M. A., Matsuura, T. and Ismail, A. F., 2014. Novel polyethersulfone (PES)/hydrous manganese dioxide (HMO) mixed matrix membranes with improved anti-fouling properties for oily wastewater treatment process. RSC Advances, 4(34), 17587-17596. https://doi.org/10.1039/c4ra00032c.
Jamshidi Gohari, R., Korminouri, F., Lau, W. J., Ismail, A. F., Matsuura, T., Chowdhury, M. N. K. et al., 2015. A novel super-hydrophilic PSf/HAO nanocomposite ultrafiltration membrane for efficient separation of oil/water emulsion. Separation and Purification Technology, 150, 13–20. https://doi.org/10.1016/j.seppur.2015.06.031.
Kumar, S., Guria, C. and Mandal, A., 2015. Synthesis, characterization and performance studies of polysulfone/bentonite nanoparticles mixed-matrix ultra-filtration membranes using oil field produced water. Separation and Purification Technology, 150, 145–158. https://doi.org/10.1016/j.seppur.2015.06.029.
Loeb, S., 2001. One hundred and thirty benign and renewable megawatts from Great Salt Lake? the possibilities of hydroelectric power by pressure-retarded osmosis. Desalination, 141, 85-91. https://doi.org/10.1016/S0011-9164(01)00392-7.
Lu, D., Liu, Q., Zhao, Y., Liu, H. and Ma, J., 2018. Treatment and energy utilization of oily water via integrated ultrafiltration-forward osmosis–membrane distillation (UF-FO-MD) system. Journal of Membrane Science, 548, 275-287. https://doi.org/10.1016/j.memsci.2017.11.004.
Mi, B. and Elimelech, M., 2010. Organic fouling of forward osmosis membranes: fouling reversibility and cleaning without chemical reagents. Journal of Membrane Science, 348, 337-345. https://doi.org/10.1016/j.memsci.2009.11.021.
Moeinzadeh, R., Emadzadeh, D. and Ghadami Jadval Ghadam, A., 2019. Petroleum effluent treatment using ultrafiltration nanocomposite membrane made of polysulfone and cellulose nanocrystal. Journal of Water and Wastewater, 31(3), 138-146. (In Persian). https://doi.org/10.22093/wwj.2019.167556.2809.
Mohammadi, T., Kazemimoghadam, M. and Saadabadi, M., 2003. Modeling of membrane fouling and flux decline in reverse osmosis during separation of oil in water emulsions. Desalination, 157(1-3), 369-375. https://doi.org/10.1016/S0011-9164(03)00419-3.
Rahimi Kashkouli, Y., Rahbari-Sisakht, M. and Mousavi Parsa, S. A., 2020. Preparation and characterization of a novel cellulose nanocrystals/polyamide thin film nanocomposite membrane for nanofiltration applications. Journal of Water and Wastewater, 32, 15-27. (In Persian). https://doi.org/10.22093/wwj.2020.229211.3014.
Rahimi Kashkouli, Y., Rahbari-Sisakht, M. and Ghadami Jadval Ghadam, A., 2019. Thin film nanocomposite nanofiltration membrane incorporated with cellulose nanocrystals with superior anti-organic fouling affinity. Environmental Science: Water Research and Technology, 6(3), 715-723. https://doi.org/10.1039/c9ew00963a.
Sarfaraz, M. V., Ahmadpour, E., Salahi, A., Rekabdar, F. and Mirza, B., 2012. Experimental investigation and modeling hybrid nano-porous membrane process for industrial oily wastewater treatment. Chemical Engineering Research and Design, 90(10), 1642-1651. https://doi.org/10.1016/j.cherd.2012.02.009.
Suleimanov, R. R., Gabbasova, I. M. and Sitdikov, R. N., 2005. Changes in the properties of oily gray forest soil during biological reclamation. Biology Bulletin, 32(1), 93-99. https://doi.org/10.1007/s10525-005-0014-5.
Tai-Hsiang, C. and Yao-Hui, H., 2018. Dehydration of waste cutting oil using a pervaporation process. Journal of the Taiwan Institute of Chemical Engineers, 82, 75-79. https://doi.org/10.1016/j.jtice.2017.08.028.
Yan, L., Li, Y. S. and Xiang, C. B., 2005. Preparation of poly(vinylidene fluoride)(pvdf) ultrafiltration membrane modified by nano-sized alumina (Al2O3) and its antifouling research. Polymer, 46(18), 7701–7706. https://doi.org/10.1016/j.polymer.2005.05.155.
Zhang, Y., Cui, P., Du, T., Shan, L. and Wang, Y., 2009. Development of a sulfated Y-doped nonstoichiometric zirconia/polysulfone composite membrane for treatment of wastewater containing oil. Separation and Purification Technology, 70(2), 153–159. https://doi.org/10.1016/j.seppur.2009.09.010.
Zhao, Y., Tan, Y., Wong, F. S., Fane, A. G. and Xu, N., 2005. Formation of dynamic membranes for oily water separation by crossflow filtration. Separation and Purification Technology, 44(3), 212-220. https://doi.org/10.1016/j.seppur.2005.01.010.
مجله آب و فاضلاب

مقالات آماده انتشار، پذیرفته شده
انتشار آنلاین از 22 آذر 1404