اکسیداسیون سونوشیمیایی رنگ اسید بلو 113 در محیط‌های آبی با استفاده از پراکسید هیدروژن و پرسولفات فعال شده با آهن فرو

نوع مقاله : مقاله پژوهشی

نویسندگان

1 استادیار گروه مهندسی بهداشت محیط، مرکز تحقیقات عوامل اجتماعی موثر بر سلامت، دانشکده بهداشت، دانشگاه علوم پزشکی همدان، همدان، ایران

2 دانش‌آموخته کارشناسی ارشد مهندسی بهداشت محیط، دانشکده بهداشت، دانشگاه علوم پزشکی همدان، همدان

3 دانش‌آموخته کارشناسی ارشد مهندسی بهداشت محیط، دانشکده بهداشت، دانشگاه علوم پزشکی همدان، همدان، ایران

4 دانش‌آموخته کارشناسی مهندسی بهداشت محیط، دانشکده بهداشت، دانشگاه علوم پزشکی همدان، همدان، ایران

چکیده

رنگ‌های آزو که در ساختار آنها حلقه‌های بنزن وجود دارد، از جمله مشکلات عمده محیط زیستی به‌شمار می‌روند. در این پژوهش تجربی کارایی فرایندهای US/H2O2/Fe2+ و US/S2O82-/Fe2+ در تخریب رنگ اسید بلو 113 مورد بررسی قرار گرفت. تأثیر پارامترهای مؤثر در فرایند، نظیر pH محلول در محدوده 3 تا 11، غلظت‌های متفاوت H2O2 و S2O82- در محدوده 1 تا 10 میلی‌مولار، اسید سولفوریک در محدوده 01/0 تا 1 میلی‌مولار و غلظت اولیه رنگ با استفاده از یک محفظه منقطع مولد التراسوند در فرکانس40 کیلوهرتز بررسی شد. همچنین تأثیر هوادهی در کارایی فرایند و تغییرات طیف UV-Vis رنگ در شرایط بهینه بررسی شد. مطابق با نتایج، با افزایش pH محیط آبی، کارایی حذف رنگ در هر دو فرایند به‌طور چشمگیری کاهش یافت، به‌طوری که بیشترین میزان حذف رنگ در هر دو فرایند در pH برابر 3 مشاهده شد. افزایش غلظت FeSO4 از 5/0 میلی مولار، کارایی حذف رنگ در هر دو فرایند را کاهش داد. در فرایند US/H2O2/Fe2+ شرایط بهینه برای حذف 5/93 درصد رنگ با غلظت اولیه 50 میلی‌گرم در لیتر در غلظت‌‌های H2O2 و FeSO4 به ترتیب 5/2 و 05/0 میلی‌مولار به‌دست آمد. در همین شرایط کارایی فرایند US/S2O82-/Fe2+ در غلظت5/2 میلی مولار S2O82-، 3/94 درصد به‌دست آمد که حاکی از تأثیر بیشتر فرایند US/S2O82-/Fe2+ در کاهش پیک 567 نانومتر ساختار رنگ نسبت به فرایند US/H2O2/Fe2+ بود. همچنین مشاهده تغییرات طیف UV-Vis رنگ اسید بلو 113 نشان داد، فرایند US/H2O2/Fe2+ نسبت به فرایند US/S2O82-/Fe2، کاهش بیشتری در پیک‌های 276 و 203 نانومتر ایجاد کرده است.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Sonochemical Oxidation of Acid Blue 113 by Fe (II)-activated Hydrogen Peroxide and Persulfate in Aqueous Environments

نویسندگان [English]

  • Abdolmotaleb Seid-Mohammadi 1
  • Ghorban Asgari 1
  • Jamal Mehr Ali Pour 2
  • amir shabanlo 3
  • Halime Almasi 2
  • Firuze Zaheri 4
1 Ass. Prof. of Environmental Health Engineering, Social Determninates of Health Research Center, Faculty of Public Health, Hamadan University of Medical Sciences, Hamadan, Iran
2 Former Graduate Student of Environmental Health Engineering, Faculty of Public Health, Hamadan University of Medical Sciences, Hamadan, Iran
3 Former Graduate Student of Environmental Health Engineering, Faculty of Public Health, Hamadan University of Medical Sciences, Hamadan, Iran
4 BS of Environmental Health Engineering, Faculty of Public Health, Hamadan University of Medical Sciences, Hamadan
چکیده [English]

Residual Azo dyes pose a major environment problem due to the benzene rings present in their structure. In this experimental study, the efficiencies of the US/H2O2/Fe2+ and US/S2O82/Fe2+ processes in degrading Acid Blue 113 Azo were investigated. For this purpose, the effects of the parameters involved in these processes such as initial solution pH in the range of 3 to 11, different concentrations of H2O2, and ‒S2O82 in the range of 1 to 10 mM, those of FeSO4 in the range of 0.1 to 1 mM, and different initial dye concenterations were investigated in a batch ultrasound reactor operated at 40 kHz. Also, the effects of aeration on process efficiency and fluctuations in the dye UV-Vis spectrum were investigated under optimum conditions. Based on the results obtained, dye removal efficiency decreased considerably in both processes with increasing pH such that maximum removal efficiency was obtained at pH 3 in both processes. Similarly dye removal efficiency decreased in both processes when FeSO4 concentration rose above 0.5 mM. The optimum conditions in the US/H2O2/Fe2+ process to achieve a removal efficiency of 93.5% for an initial dye concentration of 50 mg/L involved H2O2 and FeSO4 concentrations of 2.5 and 0.05 mM, respectively. Under the same optimal conditions, the efficiency of the US/S2O82/Fe2+ process was found to be 94.3% for a S2O82 concentration of 2.5 nM. These results suggest that the US/S2O82/Fe2+ is more effective than the US/H2O2/Fe2+ in reducing the 567 nm peak of the dye structure. Finally, examination of the changes in the UV-Vis spectra of Acid Blue 113 showed that the US/H2O2/Fe2+ process led to greater declines in the 276 and 203 nm peaks.

کلیدواژه‌ها [English]

  • Sonochemical Oxidation
  • Hydrogen peroxide
  • Persulfate
  • Acid Blue 113
  • Aqueous Environments
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