بهینه‌سازی فرایند پروکسون برای تصفیه پساب کاغذسازی با استفاده از روش Box-Behnken Design

مقالات آماده انتشار

نوع مقاله : مقاله پژوهشی

نویسندگان

استادیار، گروه مهندسی شیمی، دانشگاه تفرش، تفرش، ایران

چکیده

بهبود و تکمیل فرایند تصفیه پساب به‌منظور استفاده مجدد و بازگردانی به خط تولید، اهمیت زیادی دارد. در این پژوهش، فرایند پراکسید هیدروژن/ ازن (پروکسون) به‌عنوان مرحله تکمیلی تصفیه پساب کارخانه کاغذسازی برای کاهش میزان اکسیژن موردنیاز شیمیایی و حذف اشریشیا کلی بررسی شد. در این راستا، از روش طراحی Box-Behnken Design بر پایه روش سطوح پاسخ برای بهینه‌سازی و بررسی اثر سه متغیر حاکم بر فرایند ازن‌زنی شامل حجم مصرفی H2O2، مقدار ازن ورودی (mg/min) O3 و مدت‌زمان ازن‌زنی (min) t، استفاده شد. نتایج نشان داد مقدار O3 و H2O2 بیشترین تأثیر را برای کاهش COD (حداکثر تا حدود 75 درصد) داشته‌اند. همچنین هر سه متغیر بر افزایش کارایی فرایند پروکسون و حتی حذف کامل E. coli نقش به‌سزایی داشته‌اند. در تعیین شرایط بهینه، مقدار O3 معادلmg/min  146، مقدار H2O2 معادل  ml2 و مدت‌زمان ازن‌زنیmin  23 کمترین مقدار COD باقیمانده mg/L 73 و هم‌زمان بیشترین کارایی (حذف 75 درصدی E. coli) پیش‌بینی شد. نتایج نشان داد با توجه به برهم‌کنش O3 و H2O2، فرایند پروکسون ضعیف‌تر از فرایند ازن‌زنی تنها عمل کرده است.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Optimization of the Peroxone Process for Paper Industry Wastewater Treatment Using the Box-Behnken Design Method

نویسندگان [English]

  • Meisam Abdolkarimi Mahabadi
  • Ahmad Bayat
Assist. Prof., Dept. of Chemical Engineering, Tafresh University, Tafresh 39518-79611, Iran
چکیده [English]

It is more important to improve and complete the wastewater process in order to reuse and return it to the production line. In this study, the hydrogen peroxide/ozone process (Peroxone) was investigated as a supplementary step in paper mill wastewater treatment to reduce the amount of chemical oxygen demand and remove E. coli. In this regard, using the Box-Behnken Design method based on the response surface method to optimize and investigate the effect of three variables governing the ozonation process, including the amount of hydrogen peroxide consumed (ml), the amount of ozone input (mg/min) and ozonation time (min) were used. The results showed that the amount of ozone and hydrogen peroxide had the greatest effect for reducing COD (up to about 75%). Also, all three variables have played a significant role in increasing the efficiency of the Peraxone process and even completely eliminating E. coli. In determining the optimal conditions, the amount of ozone (146 mg/min), the amount of hydrogen peroxide (2ml) and the duration of ozonation (23 min), the lowest amount of residual COD (73 mg/L) and the highest efficiency (75% removal of E. coli) are predicted. The results showed that due to the interaction of ozone and hydrogen peroxide, the peroxone process performed weaker than the ozonation process alone.

کلیدواژه‌ها [English]

  • Peroxone
  • Wastewater Treatment
  • Experimental Design
  • Paper Industry

مراجع

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